{ "items" : [ { "id" : "http://www.idref.fr/210612681/id" "properties" : { "http://www.w3.org/1999/02/22-rdf-syntax-ns#type" : [ "http://purl.org/vocab/frbr/core#Work", "http://rdaregistry.info/Elements/c/C10001" ] , "http://id.loc.gov/vocabulary/relators/ths" : [ "http://www.idref.fr/159058007/id", "http://www.idref.fr/170726061/id", "http://www.idref.fr/159770688/id", "http://www.idref.fr/070694702/id", "http://www.idref.fr/161792502/id" ] , "http://id.loc.gov/vocabulary/relators/pra" : [ "http://www.idref.fr/143365452/id" ] , "http://id.loc.gov/vocabulary/relators/aut" : [ "http://www.idref.fr/183598792/id" ] , "http://www.w3.org/2004/02/skos/core#altLabel" : [ "Phosphorous coordination chemistry to group 11 metals, improvements in C-N cross-coupling catalyzed by Cu(I) and new polyphosphinic complexes of Au(I)" ] , "http://purl.org/dc/elements/1.1/subject" : [ "Ligand hybride", "Ligands", "Cuivre", "Compos\u00E9s de coordination", "Catalyse", "Th\u00E8ses et \u00E9crits acad\u00E9miques", "Aurophilie", "Or", "Polyphosphine ferroc\u00E9nique", "Chimie de coordination" ] , "http://www.w3.org/2004/02/skos/core#prefLabel" : [ "Chimie de coordination du phosphore aux m\u00E9taux du groupe 11, progr\u00E8s en catalyse de couplage C-N au Cu(I) et nouveaux complexes polyphosphines de l'Au(I)" ] , "http://purl.org/dc/terms/language" : [ "http://lexvo.org/id/iso639-3/fra" ] , "http://purl.org/dc/terms/subject" : [ "http://www.idref.fr/027253139/id", "http://www.idref.fr/027426629/id", "http://www.idref.fr/02767276X/id", "http://www.idref.fr/031153844/id", "http://www.idref.fr/02728302X/id", "http://www.idref.fr/027359727/id" ] , "http://purl.org/dc/elements/1.1/title" : [ "Chimie de coordination du phosphore aux m\u00E9taux du groupe 11, progr\u00E8s en catalyse de couplage C-N au Cu(I) et nouveaux complexes polyphosphines de l'Au(I)" ] , "http://id.loc.gov/vocabulary/relators/dgg" : [ "http://www.idref.fr/02819005X/id" ] , "http://id.loc.gov/vocabulary/relators/opn" : [ "http://www.idref.fr/066932416/id" ] , "http://www.w3.org/2004/02/skos/core#note" : [ "De nos jours et depuis quelques ann\u00E9es maintenant, le principe de d\u00E9veloppement durable encourage les chimistes de tous horizons \u00E0 d\u00E9velopper de nouvelles m\u00E9thodes de synth\u00E8se \u00E9conomiques et \u00E9cologiques, les ressources naturelles de notre plan\u00E8te ne sont pas illimit\u00E9es. Parmi les ressources les plus exploit\u00E9es, nous trouvons le p\u00E9trole et le gaz. Outre ces derniers et le gaz, les m\u00E9taux pr\u00E9cieux sont \u00E9galement devenus indispensables.Cette th\u00E8se se concentre sur la valorisation de complexes de cuivre et d\u2019or, obtenus \u00E0 partir de ligands phosphor\u00E9s synth\u00E9tis\u00E9s au sein du laboratoire. Dans un premier temps, nous verrons la mise au point d\u2019une r\u00E9action de N-arylation de pyrazoles catalys\u00E9e par un complexe de cuivre portant un ligand hybride phosphinoalc\u00E8ne. Dans un deuxi\u00E8me temps, les propri\u00E9t\u00E9s de coordination de l\u2019or \u00E0 diff\u00E9rentes polyphosphines ferroc\u00E9niques seront \u00E9tudi\u00E9es. Plusieurs complexes innovants seront mis en \u00E9vidence et pourront \u00EAtre utilis\u00E9s dans le cadre de futures \u00E9tudes de catalyse, ou de luminescence.", "Nowadays, sustainable development encourages chemists to develop new economic and ecologic synthesis, because natural ressources are reducing. Most exploited ressources are gas and petroleum, but precious metals are also essential. This thesis is focusing on the enhancement of gold and copper complexes, obtained in our laboratory from phosphorous-based ligands. In the first part, we will develop a new system for the N-arylation of pyrazoles from a copper complexe coordinated by a new hybrid phosphinoalkene ligand. In the second part, coordination properties of gold to different ferrocenic polyphosphine will be studied. Several new innovative complexes will be isolated, and could be used in future catalytic or luminescent studies." ] , "http://purl.org/dc/elements/1.1/type" : [ "Text" ] , "http://iflastandards.info/ns/isbd/elements/P1001" : [ "http://iflastandards.info/ns/isbd/terms/contentform/T1009" ] , "http://rdaregistry.info/Elements/w/P10219" : [ "2014" ] , "http://rdaregistry.info/Elements/u/P60049" : [ "http://rdaregistry.info/termList/RDAContentType/1020"] } } }